V-Flyer

Is it usually possible (spare seats permitting) to just buy an upgrade with FC miles at the check-in (from PE to UC)?

Thanks.

See here

Not unless you are on an upgradeable fare, as not all VS fare can be upgraded using miles.

When you book VS flight online, it now tells you if your fare is upgradable using miles during the booking process.

Regards

There is no harm in asking (nicely) and you might get lucky, you might not.

It has been reported that asking at the ticket desk can be pleasantly rewarding. It seems that all the rules go out the window at T-3 hours.